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K. John and G. S. Krishna Rao, Proc. Indian Acad. Sci, Sect. A , 1978, 87, 235. 67 G. Reynolds and E. Rodriguez, Phytochemistry, 1979,18, 1567. C. D. Poulter, E. A. Mash, J. C. Argyle, 0. J. Muscio, and H. C. Rilling, J. Am. Chem. , 1979,101, 6761. 65 66 A cyclic Terpen o ids 33 OH ments with [ 1-3H] -2-fluoro- and -2,2-difluoro-isopentenyl pyrophosphates which suggest that the popular X-group mechanism for enzymic coupling of isopentenyl and dimethylallyl pyrophosphates may not be correct. Using avian liver farnesyl pyrophosphate synthetase, no positive evidence for either free or enzyme-bound X-group intermediates ( 9 4 ) was found.
Caccamese and K. L. , Experientia, 1978, 34, 1129. l Z 5 L. J . Altman, R. C. Kowerski, and D. R . Laungani, J. A m . Chem. , 1978, 100, 6174. 126 M. A. Golub, M. L. Rosenberg, and R. V. Gemmer, Appl. Polym. , 1978, 87. l Z 7 J . Ernst and J . H . Fuhrhop, Justus LiebigsAnn. , 1979, 1635. c. '28 The C26-C35and C39 compounds were synthesized for reference purposes. " J. Albraiges, J. Borbon, and P. , 1978, 595. Y. Fujita, T. Onishi, and T. Nishida, Synthesis, 1978,934. Fujita, S. Amiya, T. Onishi, and T.
W. Underhill, W. Steck, M. D. Chisholm, H. A. Worden, and J. A. G. Howe, Can. , 1978, 110, 495.